Surface Functionalization Achieved by Photo-Initiated Thiol-Ene Chemistry
نویسندگان
چکیده
منابع مشابه
One-pot synthesis of colloidal silicon quantum dots and surface functionalization via thiol-ene click chemistry.
A solution method for preparing surface functionalized colloidal silicon quantum dots (SiQDs) is presented. SiQDs prepared by this method are reasonably monodispersed and can be further functionalized via thiol-ene click reactions to introduce specific functionalities (i.e. -NH(2), -COOH, -SO(3)(-), alkane, alkene).
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Syndiotactic 1,2 polybutadiene nanoparticles (volume average diameter 13 nm) were func tionalized in aqueous dispersion by free radical mercaptan addition. By appropriate choice of both water soluble radical initiator andmercaptan concentration, nanoparticles with a degree of functionalization of up to 85% were prepared using 3 mercaptopropionic acid methyl ester and 3 mercaptopropionic acid. O...
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As a tribute to Professor Charlie Hoyle, we take the opportunity to review the impact of thiol-ene chemistry on polymer and materials science over the past 5 years. During this time, a renaissance in thiol-ene chemistry has occurred with recent progress demonstrating its unique advantages when compared with traditional coupling and functionalization strategies. Additionally, the robust nature o...
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ژورنال
عنوان ژورنال: MRS Bulletin
سال: 2010
ISSN: 0883-7694,1938-1425
DOI: 10.1557/mrs2010.628